Porphyrin and Phthalocyanine Chemistry
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Abstract
Abstract
Metallophthalocyanine complexes bearing four non-peripheral 4-acetamidophenol substituents were synthesized with Co(II), Cu(II) and Ni(II) metal centers and characterized by FT-IR, UV-Vis,1H-NMR and MALDI-TOF-MS techniques. The photostability of the complexes was evaluated experimentally in DMSO and further supported by computational studies. All complexes exhibited high photostability, with photodegradation quantum yields following the order CoPc-4 CuPc-5 > NiPc-6 as a consequence of the d-electron configuration of the metal center and thus may influence how much absorbed energy is dissipated as heat before photodegradation can occur.
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@article{Akbulut2026peripheral,
title = {Non-peripheral 4-acetamidophenol-substituted phthalocyanines of Co(II), Cu(II) and Ni(II): Synthesis, photodegradation and TD-DFT studies},
author = {Tuğçe Akbulut and Bekir Salih and Samson Khene and Mevlüde Canlıca},
journal = {Journal of Coordination Chemistry},
year = {2026},
doi = {10.1080/00958972.2026.2718531},
url = {https://doi.org/10.1080/00958972.2026.2718531}
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