Structural and Chemical Analysis of Organic and Inorganic Compounds
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Abstract
Abstract
We carried out methanolysis of dichlorodiazadienes synthesized on the basis of 4-methylbenzaldehyde and as a result of the reaction it was determined that both isomers E/Z of methyl(Z)-2-(2-phenylhydrazineylidene)-2-(p-tolyl) acetate derivatives were obtained.The structures of the obtained compounds were confirmed by NMR and X-ray method.Compared to the E isomer, in the Z isomer, the hydrogen atom of the imine group formed an intramolecular hydrogen bond with the carbonyl group of the ester, which was reflected in the molecular structure.Taking this into account, we proposed two possible mechanisms of the reaction.Based on nucleophilic addition and nucleophilic substitution reactions, we have shown that E/Z isomers have S-cisoid, Stransoid configurations, which is clearly visible in molecular structures.Thus, we proposed a new convenient method for the synthesis of aryl hydrazones of αketo acid esters from the solvolysis reaction of dichlorodiazadienes in alcohol.Based on the fact that the arylhydrazones of α-keto acid esters obtained as a result of the reaction have many antimicrobial, bactericidal and fungicidal properties, it is worth noting that they are important compounds from the point of view of organic synthesis and pharmacological chemistry.
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@article{Shikhaliyev2026METHANOLYSIS,
title = {METHANOLYSIS OF DICHLORODIAZADIENES SYNTHESIZED BASED ON 4-METHYLBENZALDEHYDE},
author = {Namiq Q. Shikhaliyev},
journal = {Journal of Baku Engineering University Advances in Chemistry and Chemical Engineering},
year = {2026},
doi = {10.30546/2521-6317.2024.301},
url = {https://doi.org/10.30546/2521-6317.2024.301}
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