Porphyrin and Phthalocyanine Chemistry
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Abstract
Abstract
Abstract Partial peripheral functionalization of the antiaromatic nickel(II) 5,15-dioxaporphyrin (NiDOP) was explored to create substituted products suitable as substrates for oligomer synthesis. Syn- and anti-type diaryl-substituted NiDOPs were synthesized from tribromo-substituted dipyrrin through Suzuki-Miyaura coupling and separated by silica gel column chromatography. The unsubstituted β-positions adjacent to the meso-oxygen atoms were further used to synthesize a β, β'-linked dimer.
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@article{Anamika2026Peripheral,
title = {Peripheral Functionalization of Antiaromatic 5,15-Dioxaporphyrin for the Synthesis of Oligomers},
author = {Kumari Anamika and Yukako Kawashige and Taiyou Tsutsumi and Shigeki Mori and Takanori Iwasaki and Soji Shimizu},
journal = {Chemistry Letters},
year = {2026},
doi = {10.1093/chemle/upag160},
url = {https://doi.org/10.1093/chemle/upag160}
}FAQ
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