Inorganic Fluorides and Related Compounds Open access Peer reviewed

Facile Synthesis of Pentafluoroorthotelluric Acid

Claire Simon, Simon Steinhauer, Anja Wiesner, Sebastian Riedel

Israel Journal of Chemistry | Jul 29, 2026

Abstract

Abstract

A one‐pot synthesis of KOTeF5 without hazardous fluorosulfonic acid is presented. KOTeF5 can easily be protonated to HOTeF5 with sulfuric acid. The intermediate KOTeF4Cl and the corresponding acid HOTeF4Cl are fully characterized. A synthesis of the important OTeF5 transfer reagents AgOTeF5 and TMSOTeF5 starting from the now readily available KOTeF5 was developed as well.

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Authors

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Claire Simon

first | Freie Universität Berlin

Simon Steinhauer

middle | Freie Universität Berlin | ORCID 0000-0001-7420-1153

Anja Wiesner

middle | Freie Universität Berlin | ORCID 0000-0001-5300-2059

Sebastian Riedel

last | Freie Universität Berlin | ORCID 0000-0003-4552-5719

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Citation

BibTeX

@article{Simon2026Facile,
  title = {Facile Synthesis of Pentafluoroorthotelluric Acid},
  author = {Claire Simon and Simon Steinhauer and Anja Wiesner and Sebastian Riedel},
  journal = {Israel Journal of Chemistry},
  year = {2026},
  doi = {10.1002/ijch.70041},
  url = {https://doi.org/10.1002/ijch.70041}
}

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