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A composite slip model for molten polymers over metallic walls partially covered with low-surface-energy coatings

Xiaohan Jia, Nicole Gerrits, Sarfraz Haider Abbasi, Antonios K. Doufas and 1 more

Journal of Rheology | Jun 5, 2026

Abstract

Abstract

Molten polymers exhibit distinct slip characteristics over high-surface-energy metallic dies and low-surface-energy polymer processing aid (PPA) coatings. In this work, a methodology is developed to quantify the composite slip of molten polymers flowing over partially coated surfaces, where slip varies spatially between coated and bare regions. The proposed model is derived from a fundamental force balance governing pressure-driven flow and incorporates a recently formulated PPA coating dynamics framework describing the adsorption and desorption of PPA particles on the die wall [Jia et al., J. Rheol. 69, 495–505 (2025)]. The methodology is validated using capillary extrusion data for a linear low-density polyethylene melt, accurately capturing the evolution of wall shear stress and slip velocity associated with dynamic PPA coverage. The results demonstrate that the composite slip model provides a physically consistent description of the coupling between interfacial coating kinetics and macroscopic slip behavior in polymer flow.

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Authors

Researchers on this paper

Xiaohan Jia

first | University of British Columbia | ORCID 0000-0002-2953-0692

Nicole Gerrits

middle | Saudi Arabia Basic Industries (United States) | ORCID 0009-0005-3503-0618

Sarfraz Haider Abbasi

middle | King Saud University

Antonios K. Doufas

middle | King Abdullah University of Science and Technology

Savvas G. Hatzikiriakos

last | University of British Columbia | ORCID 0000-0002-1456-7927

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Citation

BibTeX

@article{Jia2026composite,
  title = {A composite slip model for molten polymers over metallic walls partially covered with low-surface-energy coatings},
  author = {Xiaohan Jia and Nicole Gerrits and Sarfraz Haider Abbasi and Antonios K. Doufas and Savvas G. Hatzikiriakos},
  journal = {Journal of Rheology},
  year = {2026},
  doi = {10.1122/8.0001200},
  url = {https://doi.org/10.1122/8.0001200}
}

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